An energy-dispersive X-ray (EDX) study of binary mixtures of mixed composition metal powders exposed to high-intensity ultrasound in decane indicates that metal particles are fused by the action of ultrasound and develop intermetallic coatings. The principal mechanism behind both processes is interparticle collision caused by the rapid movement of particles propelled by shockwaves generated at cavitation sites. By examination of systems with differing metallurgical compatibilities (Ni/Co, Cu/Cr, and Cu/Mo), it has been determined that the intermetallic coatings are generated by both adhesive wear and direct impact. The mechanisms of ultrasound-induced coatings are discussed.
Issue Section:
Technical Briefs
1.
Arnell, R. D., Davies, P. B., Halling, J., and Whomes, T. L., 1991, Tribology: Principles and Design Applications, Springer-Verlag, New York, NY, p. 69.
2.
Boudjouk, P., 1988, “Heterogeneous Sonochemistry,” Ultrasound: Its Chemical, Physical, and Biological Effects, Suslick, K. S., ed., VCH Publishers, New York, NY, pp. 165–226.
3.
Bhushan, B., and Gupta, B. K., 1991, Handbook of Tribology, McGraw-Hill, New York, NY, Vol. 3, pp. 22–30.
4.
Doktycz
S. J.
Suslick
K. S.
1990
, “Interparticle Collisions Driven by Ultrasound
,” Science
, Vol. 247
, pp. 1067
–1069
.5.
Flynn, H. G., 1964, “Physics of Acoustic Cavitation in Liquids,” Physical Acoustics, Mason, W. P., ed., Academic Press, New York, NY, Vol. IB, pp. 57–172.
6.
Hansen, M., 1958a, Constitution of Binary Alloys, 2nd ed., McGraw-Hill, New York, NY, pp. 524–525.
7.
Hansen, M., 1958b, Constitution of Binary Alloys, 2nd ed., McGraw-Hill, New York, NY, p. 600.
8.
Prosperetti
A.
1984
, “Bubble Phenomena in Sound Fields: Part Two
,” Ultrasonics
, Vol. 22
, pp. 115
–124
.9.
Rabinowicz
E.
1971
, “The Determination of the Compatibility of Metals Through Static Friction Tests
,” ASLE Trans.
, Vol. 14
, pp. 198
–205
.10.
Rabinowicz, E., 1984, CRC Handbook of Lubrication Theory and Practice of Tribology, Vol. 2, Theory and Design, Booser, E. R., ed., CRC Press, Boca Raton, FL, pp. 201–225.
11.
Suslick
K. S.
Casadonte
D. J.
1987
, “Heterogeneous Sonocatalysis with Nickel Powder
,” J. Am. Chem. Soc
, Vol. 109
, pp. 3459
–3461
.12.
Suslick, K. S., Casadonte, D. J., Choe, S. B., Cichowlas, A. A., Doktycz, S. J., Ghosh, C. K., and Grinstaff, M. W., 1990a, “Heterogeneous Sonochemistry and Sonocatalysis,” Materials Research Society Proceedings pp. 209–212.
13.
Suslick
K. S.
Doktycz
S. J.
Flint
E. B.
1990
b, “On the Origin of Sonoluminescence and Sonochemistry
,” Ultrasonics
, Vol. 28
, pp. 280
–290
.14.
Sweet
J. D.
Casadonte
D. J.
1994
, “Sonochemical Formation of Intermetallic Coatings
,” Chem. of Materials
, 6
, 2113
2113
.
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