The tribological properties of polytetrafluoroethylene (PTFE)/expanded graphite (EG) nanocomposites were evaluated on a pin-on-disk wear tester under dry conditions for the first time. Scanning electron microscopy (SEM) was used to examine worn surfaces and debris of the worn samples. The wear rate and coefficient of friction of 2 wt. % EG filled nanocomposite were reduced approximately 162 times and 38%, respectively. The significant decrease in wear rate was attributed to a thin and tenacious transfer film on the counter-surface. However, when 5 wt. % EG was filled into the PTFE/EG nanocomposite, the wear rate did not decrease further.

References

1.
Rae
,
P. J.
, and
Dattelbaum
,
D. M.
,
2004
, “
The Properties of Polytetrafluroethylene in Compression
,”
Polymer
,
45
(
22
), pp.
7615
7625
.10.1016/j.polymer.2004.08.064
2.
Deli
,
D.
,
Qunji
,
X.
, and
Hongli
,
W.
,
1989
, “
Study of the Wear of Filled Polytetrafluoroethylene
,”
Wear
,
134
(
2
), pp.
283
295
.10.1016/0043-1648(89)90131-2
3.
Goyal
,
R. K.
,
Tiwari
,
A. N.
, and
Negi
,
Y. S.
,
2008
, “
High Performance Nanocomposites for Tribological Applications: Preparation and Characterization
,”
Mater. Sci. Eng. A
,
486
(
1–2
), pp.
602
610
.10.1016/j.msea.2007.09.047
4.
Sawyer
,
W. G.
,
Freudenberg
,
K. D.
,
Bhimaraj
,
P.
, and
Schadler
,
L. S.
,
2003
, “
A Study on the Friction and Wear Behavior of PTFE Filled With Alumina Nanoparticles
,”
Wear
,
254
(
5–6
), pp.
573
580
.10.1016/S0043-1648(03)00252-7
5.
Li
,
F.
,
Hu
,
K.-A.
,
Lin
,
J.-J.
, and
Zhao
,
B. Y.
,
2002
, “
The Friction and Wear Characteristics of Nanometer ZnO Filled Polytetrafluoroethylene
,”
Wear
,
249
(
10–11
), pp.
877
882
.10.1016/S0043-1648(01)00816-X
6.
Burris
,
D. L.
,
Boesl
,
B.
,
Bourne
,
G. R.
, and
Sawyer
,
W. G.
,
2007
, “
Polymeric Nanocomposites for Tribological Applications
,”
Macromol. Mater. Eng.
,
292
(
4
), pp.
387
402
.10.1002/mame.200600416
7.
Tanaka
,
K.
, and
Kawakami
,
S.
,
1982
, “
Effect of Various Fillers on the Friction and Wear of Polytetrafluoroethylene Based Composites
,”
Wear
,
79
(
2
), pp.
221
234
.10.1016/0043-1648(82)90170-3
8.
Wang
,
Y.
, and
Yan
,
F.
,
2006
, “
Tribological Properties of Transfer Films of PTFE Based Composites
,”
Wear
,
261
(
11–12
), pp.
1359
1366
.10.1016/j.wear.2006.03.050
9.
Shi
,
Y. J.
,
Feng
,
X.
,
Wang
,
H. Y.
,
Liu
,
C.
, and
Lu
,
X. H.
,
2007
, “
Effects of Filler Crystal Structure and Shape on the Tribological Properties of PTFE Composites
,”
Tribol. Int.
,
40
(
7
), pp.
1195
1203
.10.1016/j.triboint.2006.12.006
10.
Zhang
,
Z.-Z.
,
Xue
,
Q.-J.
,
Liu
,
W.-M.
, and
Shen
,
W.-C.
,
1997
, “
Friction and Wear Properties of Metal Powder Filled PTFE Composites Under Oil Lubricated Conditions
,”
Wear
,
210
(
1–2
), pp.
151
156
.10.1016/S0043-1648(97)00052-5
11.
Shi
,
Y.
,
Feng
,
X.
,
Wang
,
H.
, and
Lu
,
X.
,
2008
, “
The Effect of Surface Modification on the Friction and Wear Behavior of Carbon Nano Fiber Filled PTFE Composites
,”
Wear
,
264
(
11–12
), pp.
934
939
.10.1016/j.wear.2007.06.014
12.
Tevruz.
,
T.
,
1998
, “
Tribological Behaviours of Carbon Filled PTFE Dry Journal Bearings
,”
Wear
,
221
(
1
), pp.
61
68
.10.1016/S0043-1648(98)00258-0
13.
Golchin
,
A.
,
Simmons
,
G. F.
, and
Glavatskih
,
S. B.
,
2012
, “
Break-Away Friction of PTFE Materials in Lubricated Conditions
,”
Tribol. Int
,
48
, pp.
54
62
.10.1016/j.triboint.2011.03.025
14.
Vail
,
J. R.
,
Krick
,
B. A.
,
Marchman
,
K. R.
, and
Swayer
,
W. G.
,
2011
, “
PTFE Fiber Reinforced PEEK Composites
,”
Wear
,
270
(
11–12
), pp.
737
741
.10.1016/j.wear.2010.12.003
15.
Xiang
,
D.
, and
Shan
,
K.
,
2006
, “
Friction and Wear Behavior of Self-Lubricating and Heavily Loaded Metal-PTFE Composites
,”
Wear
,
260
(
9–10
), pp.
1112
1118
.10.1016/j.wear.2005.07.017
16.
Li
,
F.
,
Yan
,
F.-Y.
,
Yu
,
L.-G.
, and
Liu
,
W.-M.
,
2000
, “
The Tribological Behaviors of Copper-Coated Graphite Filled PTFE Composites
,”
Wear
,
237
(
1
), pp.
33
38
.10.1016/S0043-1648(99)00303-8
17.
Burris
,
D. L.
, and
Sawyer
,
W. G.
,
2007
, “
Tribological Behavior of PEEK Components With Compositionally Graded PEEK/PTFE Surfaces
,”
Wear
,
262
(
1–2
), pp.
220
224
.10.1016/j.wear.2006.03.045
18.
Yuan
,
X.-D.
, and
Yang
,
X.-J.
,
2010
, “
A Study on Friction and Wear Properties of PTFE Coatings Under Vacuum Conditions
,”
Wear
,
269
(
3–4
), pp.
291
297
.10.1016/j.wear.2010.04.014
19.
Misra
,
R.D.K.
,
Nerikar
,
P.
,
Bertrand
,
K.
, and
Murphy
,
D.
,
2004
, “
Some Aspects of Surface Deformation and Fracture of 5–20% Calcium Carbonate-Reinforced Polyethylene Composites
,”
Mater. Sci. Eng. A
,
384
(
1–2
), pp.
284
298
.10.1016/j.msea.2004.06.047
20.
Hadal
,
R. S.
, and
Misra
,
R.D.K.
,
2004
, “
The Influence of Loading Rate and Concurrent Microstructural Evolution in Micrometric Talc- and Wollastonite-Reinforced High Isotactic Polypropylene Composites
,”
Mater. Sci. Eng. A
,
374
(
1–2
), pp.
374
389
.10.1016/j.msea.2004.03.035
21.
Dasari
,
A.
,
Rohrmann
,
J.
, and
Misra
,
R.D.K.
,
2004
, “
On the Scratch Deformation of Micrometric Wollastonite Reinforced Polypropylene Composites
,”
Mater. Sci. Eng. A
,
364
(
1–2
), pp.
357
369
.10.1016/j.msea.2003.08.058
22.
Blanchet
,
T. A.
,
Kandanur
,
S. S.
, and
Schadler
,
L. S.
,
2010
, “
Coupled Effect of Filler Content and Counter Surface Roughness on PTFE Nanocomposite Wear Resistance
,”
Tribol. Lett.
,
40
(
1
), pp.
11
21
.10.1007/s11249-009-9519-2
23.
Goyal
,
R. K.
,
Jagdale
,
P. A.
, and
Mulik
,
U. P.
,
2008
, “
Thermal, Mechanical, and Dielectric Properties of Polystyrene/Expanded Graphite Nanocomposites
,”
J. Appl. Polym. Sci.
,
111
(
4
), pp.
2071
2077
.10.1002/app.29042
24.
Biswas
,
S. K.
, and
Vijayan
,
K.
,
1992
, “
Friction and Wear of PTFE—A Review
,”
Wear
,
158
(
1–2
), pp.
193
211
.10.1016/0043-1648(92)90039-B
25.
Wieleba
,
W.
,
2007
, “
The Mechanism of Tribological Wear of Thermoplastic Materials
,”
Arch. Civil Mech. Eng.
,
8
, pp.
185
199
.10.1016/S1644-9665(12)60236-2
26.
Chen
,
W. X.
,
Li
,
F.
,
Han
,
G.
,
Xia
,
J. B.
,
Wang
,
L. Y.
,
Tu
,
J. P.
, and
Xu
,
Z. D.
,
2003
, “
Tribological Behavior of Carbon Nanotube Filled PTFE Composites
,”
Tribol. Lett.
,
15
(
3
), pp.
275
278
.10.1023/A:1024869305259
27.
McElwain
,
S. E.
,
Blanchet
,
T. A.
,
Schadler
,
L. S.
, and
Sawyer
,
W. G.
,
2008
, “
Effect of Particle Size on the Wear Resistance of Alumina Filled PTFE Micro- and Nanocomposites
,”
Tribol. Trans.
,
51
(
3
), pp.
247
251
.10.1080/10402000701730494
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