Abstract

Calcium carbonate powder comprising uniform nanoparticles of novel morphology was synthesized under extensively optimized trial parameters. The as-prepared ultrafine rod shape CaCO3 particles after characterizations were used as an antiwear/antifriction additive in commercial lithium grease (CLG) of different specifications. The effect of the added particles on the antifriction and antiwear properties of the blended commercial greases was explored by using a ball-on-disk tribometer. The observed data were compared with the additized grease having commercially available CaCO3 powder. Results exposed that uniformity in particle size and shape is a key factor for the improvement of tribological properties and reproducibility of the experimental results. Therefore, the as-prepared monodispersed rod shapes CaCO3 particles as additives considerably improved the tribological properties of the CLG as compared with the irregular particles of the commercial calcium carbonate. These blends showed the best results at the optimum amount of 3 wt% of the added CaCO3 particles. Among the three selected greases, the additized Momin grease exhibited best antiwear/antifriction performance as compared with the additized Awami and Sinopec greases.

References

1.
Wu
,
Y. Y.
,
Tsui
,
W. C.
, and
Liu
,
T. C.
,
2007
, “
Experimental Analysis of Tribological Properties of Lubricating Oils With Additives
,”
Wear
,
262
(
7–8
), pp.
819
825
. 10.1016/j.wear.2006.08.021
2.
Rai
,
M.
,
Yadav
,
A.
, and
Gade
,
A.
,
2009
, “
Silver Nanoparticles as a New Generation of Antimicrobials
,”
Biotechnol. Adv.
,
27
(
1
), pp.
76
83
. 10.1016/j.biotechadv.2008.09.002
3.
Shan
,
D.
,
Zhu
,
M.
,
Xue
,
H.
, and
Cosnier
,
S.
,
2007
, “
Development of the Amperometric Biosensor for Glucose Based on a Novel Attractive Enzyme Immobilization Matrix: Calcium Carbonate Nanoparticles
,”
Biosens. Bioelectron.
,
22
(
8
), pp.
1612
1617
. 10.1016/j.bios.2006.07.019
4.
Saraya
,
M. E.
, and
Rokbaa
,
H. H.
,
2016
, “
Preparation of Vaterite Calcium Carbonate in the Form of Spherical Nano-Size Particles With the Aid of Polycarboxylate Super Plasticizer as a Capping Agent
,”
Am. J. Nanomater.
,
4
(
2
), pp.
44
51
.
5.
Chen
,
P.
,
Wang
,
J.
,
Wang
,
L.
,
Xu
,
Y.
,
Qian
,
X.
, and
Ma
,
H.
,
2017
, “
Producing Vaterite by CO2 Sequestration in the Waste Solution of Chemical Treatment of Recycled Concrete Aggregates
,”
J. Cleaner Prod.
,
149
, pp.
735
742
. 10.1016/j.jclepro.2017.02.148
6.
Xu
,
N.
,
Zhang
,
M.
,
Li
,
W.
,
Zhao
,
G.
,
Wang
,
X.
, and
Liu
,
W.
,
2013
, “
Study on the Selectivity of Calcium Carbonate Nanoparticles Under the Boundary Lubrication Condition
,”
Wear
,
307
(
1–2
), pp.
35
43
. 10.1016/j.wear.2013.07.010
7.
Ji
,
X.
,
Chen
,
Y.
,
Zhao
,
G.
,
Wang
,
X.
, and
Liu
,
W.
,
2011
, “
Tribological Properties of CaCO3 Nanoparticles as an Additive in Lithium Grease
,”
Tribol Lett.
,
41
(
1
), pp.
113
119
. 10.1007/s11249-010-9688-z
8.
Kim
,
S. K.
,
Foote
,
M. B.
, and
Huang
,
L.
,
2013
, “
Targeted Delivery of EV Peptide to Tumor Cell Cytoplasm Using Lipid-Coated Calcium Carbonate Nanoparticles
,”
Cancer Lett.
,
334
(
2
), pp.
311
318
. 10.1016/j.canlet.2012.07.011
9.
Ghaedamini
,
H.
, and
Amiri
,
M. C.
,
2019
, “
Effects of Temperature and Surfactant Concentration on the Structure and Morphology of Calcium Carbonate Nanoparticles Synthesized in a Colloidal Gas System
,”
J. Mol. Liq.
,
282
, pp.
213
220
. 10.1016/j.molliq.2019.02.119
10.
Shimpi
,
N. G.
,
Mali
,
A. D.
,
Hansora
,
D. P.
, and
Mishra
,
S.
,
2015
, “
Synthesis and Surface Modification of Calcium Carbonate Nanoparticles Using Ultrasound Cavitation Technique
,”
Nanosci. Nanoeng.
,
3
(
1
), pp.
8
12
.
11.
Mishra
,
S.
,
Shimpi
,
N. G.
, and
Mali
,
A. D.
,
2012
, “
Investigation of Photo-Oxidative Effect on Morphology and Degradation of Mechanical and Physical Properties of Nano CaCO3 Silicone Rubber Composites
,”
Polym. Adv. Technol.
,
23
(
2
), pp.
236
246
. 10.1002/pat.1861
12.
Wang
,
W. Z.
,
Wang
,
G. H.
,
Liu
,
Y. K.
,
Zheng
,
C. L.
, and
Zhan
,
Y. J.
,
2009
, “
Synthesis and Characterization of Aragonite Whiskers by a Novel and Simple Route
,”
J. Mater. Chem.
,
11
(
6
), pp.
1752
1754
. 10.1039/b100556l
13.
Kang
,
F.
,
Wang
,
D.
,
Pu
,
Y.
,
Zeng
,
X. F.
,
Wang
,
J. X.
, and
Chen
,
J. F.
, “
Efficient Preparation of Monodisperse CaCO3 Nanoparticles as Overbased Nanodetergents in a High-Gravity Rotating Packed Bed Reactor
,”
Powder Technol.
,
325
, pp.
405
411
. 10.1016/j.powtec.2017.11.036
14.
Gusain
,
R.
,
Gupta
,
P.
,
Saran
,
S.
, and
Khatri
,
O. P.
,
2014
, “
Halogen-free bis (Imidazolium)/bis (Ammonium)-di[bis (Salicylate) Borate] Ionic Liquids as Energy-Efficient and Environmentally Friendly Lubricant Additives
,”
ACS Appl. Mater. Interfaces
,
6
(
17
), pp.
15318
15328
. 10.1021/am503811t
15.
Jatti
,
V. S.
, and
Singh
,
T. P.
,
2015
, “
Copper Oxide Nano-Particles as Friction-Reduction and Anti-Wear Additives in Lubricating Oil
,”
J. Mech. Sci. Technol.
,
29
(
2
), pp.
793
798
. 10.1007/s12206-015-0141-y
16.
Shahnazar
,
S.
,
Bagheri
,
S.
, and
Hamid
,
S. B. A.
,
2016
, “
Enhancing Lubricant Properties by Nanoparticle Additives
,”
Int. J. Hydrogen Energy
,
41
(
4
), pp.
3153
3170
. 10.1016/j.ijhydene.2015.12.040
17.
Zhang
,
X.
,
Sun
,
W.
,
Ma
,
H.
,
Xu
,
H.
, and
Dong
,
J.
,
2014
, “
Investigation of the Tribological Properties of Two Different Layered Sodium Silicates Utilized as Solid Lubrication Additives in Lithium Grease
,”
Ind. Eng. Chem. Res.
,
53
(
1
), pp.
182
188
. 10.1021/ie402481u
18.
Chao
,
M.
,
Li
,
W.
,
Chen
,
L.
, and
Wang
,
X.
,
2015
, “
Hindered Phenol Derivative as a Multifunctional Additive in Lithium Complex Grease
,”
Ind. Eng. Chem. Res
,
54
(
26
), pp.
6605
6610
. 10.1021/acs.iecr.5b00374
19.
Kamel
,
B. M.
,
Mohamed
,
A.
,
El-Sherbiny
,
M.
,
Abed
,
K. A.
, and
Abd-Rabou
,
M.
,
2017
, “
Tribological Properties of Graphene Nanosheets as an Additive in Calcium Grease
,”
J. Dispersion Sci. Technol.
,
38
(
10
), pp.
495
1500
. 10.1080/01932691.2016.1257390
20.
Mohamed
,
A.
,
Osman
,
T. A.
,
Khattab
,
A.
, and
Zaki
,
M.
,
2014
, “
Tribological Behavior of Carbon Nanotubes as an Additive on Lithium Grease
,”
ASME J. Tribol.
,
137
(
1
), pp.
011801
011805
. 10.1115/1.4028225
21.
Ali
,
M. K. A.
,
Xianjun
,
H.
,
Mai
,
L.
,
Qingping
,
C.
,
Turkson
,
R. F.
, and
Bicheng
,
C.
,
2016
, “
Improving the Tribological Characteristics of Piston Ring Assembly in Automotive Engines Using Al2O3 and TiO2 Nanomaterials as Nano-Lubricant Additives
,”
Tribol. Int.
,
103
, pp.
540
554
. 10.1016/j.triboint.2016.08.011
22.
Chang
,
H.
,
Lan
,
C. W.
,
Chen
,
C. H.
,
Kao
,
M. J.
, and
Guo
,
J. B.
,
2014
, “
Anti-wear and Friction Properties of Nanoparticles as Additives in the Lithium Grease
,”
Int. J. Precis. Eng. Manuf.
,
15
(
10
), pp.
2059
2063
. 10.1007/s12541-014-0563-y
23.
Ge
,
X.
,
Xia
,
Y.
, and
Cao
,
Z.
,
2015
, “
Tribological Properties and Insulation Effect of Nanometer TiO2 and Nanometer SiO2 as Additives in Grease
,”
Tribol. Int.
,
92
, pp.
454
461
. 10.1016/j.triboint.2015.07.031
24.
He
,
Q.
,
Li
,
A.
,
Guo
,
Y.
,
Liu
,
S.
,
Zhang
,
Y.
, and
Kong
,
L.
,
2018
, “
Tribological Properties of Nanometer Cerium Oxide as Additives in Lithium Grease
,”
J. Rare Earths
,
36
(
2
), pp.
209
214
. 10.1016/j.jre.2017.09.004
25.
Zhang
,
M.
,
Wang
,
X.
,
Fu
,
X.
, and
Xia
,
Y.
,
2009
, “
Performance and Anti-Wear Mechanism of CaCO3 Nanoparticles as a Green Additive in Poly-Alpha-Olefin
,”
Tribol. Int.
,
42
(
7
), pp.
1029
1039
. 10.1016/j.triboint.2009.02.012
26.
Jin
,
D.
, and
Yue
,
L.
,
2008
, “
Tribological Properties Study of Spherical Calcium Carbonate Composite as Lubricant Additive
,”
Mater. Lett.
,
62
(
10–11
), pp.
1565
1568
. 10.1016/j.matlet.2007.09.023
27.
Caixiang
,
G.
,
Qingzhu
,
L.
,
Zhuoming
,
G.
, and
Guangyao
,
Z.
,
2008
, “
Study on Application of CeO2 and CaCO3 Nanoparticles in Lubricating Oils
,”
J. Rare Earths
,
26
(
2
), pp.
163
167
. 10.1016/S1002-0721(08)60058-7
28.
Zhao
,
G.
,
Zhao
,
Q.
,
Li
,
W.
,
Wang
,
X.
, and
Liu
,
W.
,
2014
, “
Tribological Properties of Nano-Calcium Borate as Lithium Grease Additive
,”
Lubr. Sci.
,
26
(
1
), pp.
43
53
. 10.1002/ls.1227
29.
Dai
,
W.
,
Kheireddin
,
B.
,
Gao
,
H.
, and
Liang
,
H.
,
2016
, “
Roles of Nanoparticles in Oil Lubrications
,”
Tribol. Int.
,
102
, pp.
88
98
. 10.1016/j.triboint.2016.05.020
30.
Akhtar
,
K.
, and
Yousafzai
,
S.
,
2019
, “
Morphology Control Synthesis of Nano Rods and Nano Ovals CaCO3 Particle Systems
,”
J. Dispersion. Sci. Technol.
,
41
(
9
), pp.
1356
1370
. 10.1080/01932691.2019.1626248
31.
Murnandari
,
A.
,
Kang
,
J.
,
Youn
,
M. H.
,
Park
,
K. T.
,
Kim
,
H. J.
,
Kang
,
S. P.
, and
Jeong
,
S. K.
,
2017
, “
Effect of Process Parameters on the CaCO3 Production in the Single Process for Carbon Capture and Mineralization
,”
Korean J. Chem. Eng.
,
34
(
3
), pp.
935
941
. 10.1007/s11814-016-0340-y
32.
Kim
,
D. W.
,
Lee
,
J. Y.
,
Lee
,
S. M.
, and
Lim
,
J. C.
,
2018
, “
Surface Modification of Calcium Carbonate Nanoparticles by Fluorosurfactant
,”
Colloids Surf., A
,
536
(
special issue
), pp.
213
223
. 10.1016/j.colsurfa.2017.05.002
33.
Burton
,
A. W.
,
Ong
,
K.
,
Rea
,
T.
, and
Chan
,
I. Y.
,
2009
, “
On the Estimation of Average Crystallite Size of Zeolites From the Scherrer Equation: A Critical Evaluation of Its Application to Zeolites With One-Dimensional Pore Systems
,”
Microporous Mesoporous Mater.
,
117
(
1–2
), pp.
75
90
. 10.1016/j.micromeso.2008.06.010
34.
Jimoh
,
O. A.
,
Okoye
,
P. U.
,
Ariffin
,
K. S.
,
Hussin
,
H. B.
, and
Baharun
,
N.
,
2017
, “
Continuous Synthesis of Precipitated Calcium Carbonate Using a Tubular Reactor With the Aid of Aloe Vera (Aloe Barbadensis Miller) Extract as a Green Morphological Modifier
,”
J. Clean. Prod.
,
150
, pp.
104
111
. 10.1016/j.jclepro.2017.02.200
35.
Gay
,
P. A.
,
Berçot
,
P.
, and
Pagetti
,
J.
,
2001
, “
Electrodeposition and Characterization of Ag-ZrOElectroplated Coatings
,”
Surf. Coat. Technol.
,
140
(
2
), pp.
147
154
. 10.1016/S0257-8972(01)01043-X
36.
Luo
,
T.
,
Wei
,
X.
,
Huang
,
X.
,
Huang
,
L.
, and
Yang
,
F.
,
2014
, “
Tribological Properties of Al2O3 Nanoparticles as Lubricating Oil Additives
,”
Ceram. Int.
,
40
(
5
), pp.
7143
7149
. 10.1016/j.ceramint.2013.12.050
37.
El Adly
,
R. A.
,
Hussein
,
M. F.
, and
Mohamed
,
A.
,
2015
, “
Preparation and Evaluation of Lubricating Greases Based on Carbon Nanotubes
,”
IJAPBC
,
4
(
3
), pp.
675
684
.
38.
Standard
,
A.
,
2000
, “Standard Test Method for Wear Testing With a Pin-on-Disk Apparatus,” Annual Book of ASTM Standards G99-05, 3.
39.
Niu
,
M.
, and
Qu
,
J.
,
2018
, “
Tribological Properties of Nano-Graphite as an Additive in Mixed Oil-Based Titanium Complex Grease
,”
RSC Adv.
,
8
(
73
), pp.
42133
42144
. 10.1039/C8RA08109C
40.
Gulzar
,
M.
,
Masjuki
,
H. H.
,
Kalam
,
M. A.
,
Varman
,
M.
,
Zulkifli
,
N. W. M.
,
Mufti
,
R. A.
, and
Zahid
,
R.
,
2016
, “
Tribological Performance of Nanoparticles as Lubricating Oil Additives
,”
J. Nanopart. Res.
,
18
(
8
), pp.
223
258
. 10.1007/s11051-016-3537-4
41.
Akhtar
,
K.
,
Hussain
,
A.
,
Gul
,
M.
,
Khalid
,
H.
, and
Yousafzai Zai
,
S.
,
2019
, “
Facile Synthesis of UniformCalcite Microcubes and Their Enhanced Tribological Performance in Lithium-Based Commercial Grease
,”
ASME J. Tribol.
,
141
(
5
), p.
052002-1-052002-9
. 10.1115/1.4042677
42.
Rapoport
,
L.
,
Lvovsy
,
M.
,
Lapser
,
I.
,
Leshchinsky
,
W.
,
Volovik
,
Y.
,
Feldman
,
Y.
, and
Tenne
,
R.
,
2001
, “
Friction and Wear of Bronze Powder Composites Including Fullerene-like WS2 Nanoparticles
,”
Wear
,
249
(
1–2
), pp.
149
156
. 10.1016/S0043-1648(01)00519-1
43.
Arumugam
,
S.
,
Baskar
,
S.
,
Sankaranarayanan
,
S.
,
Athreya
,
S. H.
,
Narayanan
,
N. L.
, and
Prasad
,
S. S. D.
,
2018
, “
Influence of Morphology of Anti-Wear Nano Additives on Tribological Behavior of Chemically Modified Rapeseed oil
,”
IOP Conf. Ser.: Mater. Sci. Eng.
,
390
(
1
), pp.
012017
012024
. 10.1088/1757-899X/390/1/012017
44.
Mansot
,
J. L.
,
Bercion
,
Y.
,
Romana
,
L.
, and
Martin
,
J. M.
,
2009
, “
Nanolubrication
,”
Braz. J. Phys.
,
39
(
1a
), pp.
186
197
. 10.1590/S0103-97332009000200011
45.
Zhmud
,
B.
, and
Pasalskiy
,
B.
,
2013
, “
Nanomaterials in Lubricants: An Industrial Perspective on Current Research
,”
Lubricants
,
1
(
4
), pp.
95
101
. 10.3390/lubricants1040095
46.
Cristea
,
G. C.
,
Cazamir
,
D.
,
Dima
,
D.
,
Georgescu
,
C.
, and
Deleanu
,
L.
,
2018
, “
Influence of TiO2 as Nano Additive in Rapeseed oil
,”
IOP Conf. Ser.: Mater. Sci. Eng.
,
444
, pp.
022011
022020
. 10.1088/1757-899X/444/2/022011
47.
Patil
,
S. J.
,
Patil
,
D. P.
,
Shrotri
,
A. P.
, and
Patil
,
V. P.
,
2014
, “
A Review on the Effect of Addition of Nanoparticles on Tribological Properties of Lubricants
,”
Int. J. Mech. Eng. Technol.
,
5
(
11
), pp.
120
129
.
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